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Benzene

Benzene: From Water Technology Volume 32, Issue 4 - April 2009

What it is:

  • Chemical symbol: C6H6. An organic chemical, benzene is one of the aromatic hydrocarbons.
  • Colorless or light yellow liquid at room temperature. Sweet odor, highly flammable.
  • Benzene dissolves easily in water: 0.8 grams per liter (800 milligrams per liter [mg/L], or 800 parts per million [ppm]), at 77 degrees F (25 C). Will float on top of water.
  • Evaporates quickly at room temperature. As a vapor, it is heavier than air. Boils at 176 degrees F (80.1 C).

Occurrence:

  • Occurs in nature from incomplete combustion of carbon-rich materials, such as in volcanoes and forest fires.
  • Natural constituent of crude oil
  • Produced from coal or petroleum (usually the latter). Ranks among the top 20 chemicals in production volume. Used to make solvents, detergents, plastics, resins, paint and many other products.
  • An ingredient of gasoline, benzene is found in groundwater contaminated by leaking underground fuel storage tanks, or in surface water subject to fuel spills. Gasoline contains a bit less than 1% benzene.
  • Occurs in very low levels in outdoor air. Slightly higher levels indoors due to paints, glues, etc. Higher also in air near exhaust emissions, service stations, places where solvents used.
  • Tobacco smoke contains benzene.
  • Released with the burning of polyvinyl chloride (PVC).

Health Effects:

  • A carcinogen in humans. Long-term exposure to heavy levels in air causes leukemia. Most at risk: people who work in industries that make or use benzene.
  • Drinking water or eating food containing high levels can cause vomiting, dizziness or death within minutes to hours.
  • Breathing in high levels over a short period can cause drowsiness, dizziness, unconsciousness and death.

Regulation:

  • US Environmental Protection Agency (EPA) Primary Drinking Water Standards maximum contaminant level (MCL) in water: 0.005 mg/L (5 parts per billion, or 5 micrograms per liter).
  • Accidental spills of benzene into the environment of greater than 10 pounds (4.5 kilograms) must be reported to EPA.
  • Precaution: Water suspected of containing benzene should not be consumed, and bottled water should be substituted until the water source is safe to drink.

Water treatment:

  • Adsorption with granular activated carbon filter.
  • Ozonation.
Sources: US EPA, US Occupational Safety and Health Administration, US Centers for Disease Control and Prevention, Clean Water Partners.